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Which of the elements listed below has the greatest electronegativity?


A) Na
B) As
C) Ga
D) Cs
E) Sb

F) B) and E)
G) All of the above

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Which one of the following is most likely to be a covalent compound?


A) CsOH
B) NF3
C) Sr(NO3) 2
D) CaO
E) LiF

F) B) and E)
G) D) and E)

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Which of the bonds below would have the greatest polarity (i.e., highest percent ionic character) ?


A) Si - P
B) Si - S
C) Si - Se
D) Si - Cl
E) Si - I

F) B) and D)
G) A) and B)

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The number of resonance structures for the sulfur dioxide molecule that satisfy the octet rule is


A) 1.
B) 2.
C) 3.
D) 4.
E) None of these.

F) None of the above
G) A) and C)

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The bond in which of the following pairs of atoms would have the greatest percent ionic character (i.e., most polar) ?


A) C - O
B) S - O
C) Na - I
D) Na - Br
E) F - F

F) B) and E)
G) C) and D)

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Which one of the following compounds does not follow the octet rule?


A) NF3
B) CF4
C) PF5
D) AsH3
E) HCl

F) A) and B)
G) A) and C)

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Use the Born-Haber cycle to calculate the lattice energy of KCl(s) given the following data: Δ\Delta H(sublimation) K = 79.2 kJ/mol I1 (K) = 418.7 kJ/mol Bond energy (Cl-Cl) = 242.8 kJ/mol EA (Cl) = 348 kJ/mol Δ\Delta H  Use the Born-Haber cycle to calculate the lattice energy of KCl(s) given the following data:  \Delta H(sublimation) K = 79.2 kJ/mol I<sub>1</sub> (K) = 418.7 kJ/mol Bond energy (Cl-Cl) = 242.8 kJ/mol EA (Cl) = 348 kJ/mol  \Delta H   (KCl(s) ) = -435.7 kJ/mol A) -165 kJ/mol B) 288 kJ/mol C) 629 kJ/mol D) 707 kJ/mol E) 828 kJ/mol (KCl(s) ) = -435.7 kJ/mol


A) -165 kJ/mol
B) 288 kJ/mol
C) 629 kJ/mol
D) 707 kJ/mol
E) 828 kJ/mol

F) A) and B)
G) A) and D)

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Of the species NO2, NO, and N2, only NO2 is an exception to the octet rule.

A) True
B) False

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The Si - Cl bond has less ionic character than the C - Cl bond.

A) True
B) False

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Which of the elements listed below is the least electronegative?


A) Sr
B) V
C) Ni
D) P
E) I

F) C) and E)
G) All of the above

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Use the Born-Haber cycle to calculate the standard enthalpy of formation ( Δ\Delta H  Use the Born-Haber cycle to calculate the standard enthalpy of formation ( \Delta H   ) for LiCl(s) given the following data:  \Delta H(sublimation) Li = 155.2 kJ/mol I<sub>1</sub> (Li) = 520 kJ/mol Bond energy (Cl-Cl) = 242.7 kJ/mol EA (Cl) = 349 kJ/mol Lattice energy (LiCl(s) ) = 828 kJ/mol A) 440 kJ/mol B) 320 kJ/mol C) -260 kJ/mol D) -380 kJ/mol E) -1420 kJ/mol ) for LiCl(s) given the following data: Δ\Delta H(sublimation) Li = 155.2 kJ/mol I1 (Li) = 520 kJ/mol Bond energy (Cl-Cl) = 242.7 kJ/mol EA (Cl) = 349 kJ/mol Lattice energy (LiCl(s) ) = 828 kJ/mol


A) 440 kJ/mol
B) 320 kJ/mol
C) -260 kJ/mol
D) -380 kJ/mol
E) -1420 kJ/mol

F) B) and D)
G) A) and E)

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How many covalent bonds will be drawn to phosphorous in PO43- for the dot structure that expands the octet to minimize formal charge and if necessary places negative formal charges on the most electronegative atom(s) ?


A) 4
B) 5
C) 6
D) 7
E) 8

F) A) and D)
G) C) and D)

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The bond in F2 is described as polar covalent.

A) True
B) False

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Which of the following ionic solids would have the largest lattice energy?


A) SrO
B) NaF
C) CaBr2
D) CsI
E) BaSO4

F) C) and E)
G) B) and E)

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Write a Lewis structure for the chlorate ion, ClO3-, that obeys the octet rule, showing all non-zero formal charges, and give the total number of resonance structures for ClO3- that obey the octet rule.

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blured image Total number of res...

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How many covalent bonds will be drawn to bromine in BrO3- for the dot structure that expands the octet to minimize formal charge and if necessary places negative formal charges on the most electronegative atom(s) ?


A) 3
B) 4
C) 5
D) 6
E) 7

F) C) and E)
G) None of the above

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Estimate the enthalpy change for the combustion of one mole of acetylene, C2H2, to form carbon dioxide and water vapor. BE(C-H) = 456 kJ/mol BE(C \equiv C) = 962 kJ/mol BE(O=O) = 499 kJ/mol BE(C=O) = 802 kJ/mol BE(O-H) = 462 kJ/mol


A) -1759 kJ/mol
B) +653 kJ/mol
C) +1010 kJ/mol
D) -1010 kJ/mol
E) -155 kJ/mol

F) C) and D)
G) B) and D)

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Calculate the energy change for the reaction K(g) + I(g) \rarr K+(g) + I - (g) Given the following ionization energy (IE) and electron affinity (EA) values.  Calculate the energy change for the reaction K(g) + I(g)  \rarr  K<sup>+</sup>(g) + I<sup> -</sup> (g)  Given the following ionization energy (IE) and electron affinity (EA) values.   A) -124 kJ/mol B) -715 kJ/mol C) 715 kJ/mol D) 1429 kJ/mol E) None of these


A) -124 kJ/mol
B) -715 kJ/mol
C) 715 kJ/mol
D) 1429 kJ/mol
E) None of these

F) C) and D)
G) B) and E)

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Which one of these polar covalent bonds would have the greatest percent ionic character?


A) H - Br
B) H - Cl
C) H - F
D) H - I

E) A) and C)
F) A) and D)

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Which of the following pairs of elements would be most likely to form an ionic compound?


A) Cl and I
B) Al and K
C) Cl and Mg
D) C and S
E) Al and Mg

F) B) and D)
G) A) and C)

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