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a. Calculate the wavelength in nm of a photon whose energy is 6.00 × 10-19 J. b. Would the photon in (a) have enough energy to ionize a hydrogen atom in its ground state (i.e., to separate the proton and electron completely)? Use the Bohr equation to explain your answer.

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a. 331 nm
b. No. 2.18 × 10-18 J i...

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For the following equations a. name the scientist to whom the equation is attributed. b. in not more than three lines, explain clearly what the equation means or represents. 1. E = nh 2. = h/mu 3. H = E 4. xmu h/4 5. Ephoton = h

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1. a. Planck
b. A black body can only em...

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According to the Rydberg equation, the line with the shortest wavelength in the emission spectrum of atomic hydrogen is predicted to lie at a wavelength (in nm) of


A) 91.2 nm.
B) 1.10 × 10-2 nm.
C) 1.10 × 102 nm.
D) 1.10 × 1016 nm.
E) none of the above.

F) B) and D)
G) D) and E)

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The shape of an atomic orbital is associated with


A) the principal quantum number (n) .
B) the angular momentum quantum number (l) .
C) the magnetic quantum number (ml) .
D) the spin quantum number (ms) .
E) the magnetic and spin quantum numbers, together.

F) C) and D)
G) A) and B)

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Who proposed a model that successfully explained the photoelectric effect?


A) Planck
B) Einstein
C) Compton
D) Rydberg
E) Bohr

F) A) and E)
G) C) and E)

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B

The ionization energy is the energy needed to remove an electron from an atom. In the Bohr model of the hydrogen atom, this means exciting the electron to the n = state. What is the ionization energy in kJ/mol, for hydrogen atoms initially in the n = 2 energy level?


A) 290 kJ/mol
B) 328 kJ/mol
C) 656 kJ/mol
D) 983 kJ/mol
E) 1311 kJ/mol

F) C) and D)
G) A) and E)

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B

Interference of light waves


A) separates light into its component colors.
B) creates a pattern of light and dark regions.
C) focuses a broad beam of light into a point.
D) bends light as it passes the edge of an object.
E) creates a laser beam.

F) A) and E)
G) B) and E)

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Which word best describes the phenomenon which gives rise to a rainbow?


A) reflection
B) dispersion
C) diffraction
D) interference
E) deflection

F) D) and E)
G) None of the above

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Select the arrangement of electromagnetic radiation which starts with the lowest wavelength and increases greatest wavelength.


A) radio, infrared, ultraviolet, gamma rays
B) radio, ultraviolet, infrared, gamma rays
C) gamma rays, radio, ultraviolet, infrared
D) gamma rays, infrared, radio, ultraviolet
E) gamma rays, ultraviolet, infrared, radio

F) C) and D)
G) B) and E)

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The Rydberg equation, giving the wavelengths of lines in the spectrum of the hydrogen atom, was obtained by assuming that energy is quantized.

A) True
B) False

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For the following orbitals, state the values or n, l and ml which apply, and draw a sketch showing the shape and orientation of the orbital. a. 3s b. 2px

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a. 3s: n = 3, l = 0,...

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A sprinter must average 24.0 mi/h to win a 100-m dash in 9.30 s. What is his wavelength at this speed if his mass is 84.5 kg?


A) 7.29 × 10-37 m
B) 3.26 × 10-37 m
C) 5.08 × 10-30 m
D) 1.34 × 10-30 m
E) none of the above

F) B) and C)
G) C) and D)

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a. What is the frequency of microwave radiation which has a wavelength of 10.7 cm? b. What is the energy of one photon of this radiation?

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a. 2.80 × 109 s-1 b. 1.86 × 10-24 J

Which scientist first proposed that particles of matter could have wave properties?


A) Einstein
B) Planck
C) de Broglie
D) Compton
E) Heisenberg

F) A) and D)
G) B) and D)

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Who was the first scientist to propose that the atom had a dense nucleus which occupied only a small fraction of the volume of the atom?


A) Planck
B) Bohr
C) Rydberg
D) Rutherford
E) Thomson

F) C) and D)
G) A) and B)

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Line spectra from all regions of the electromagnetic spectrum, including the Paschen series of infrared lines for hydrogen, are used by astronomers to identify elements present in the atmospheres of stars. Calculate the wavelength of the photon emitted when the hydrogen atom undergoes a transition from n = 5 to n = 3. (R = 1.096776 × 107 m-1)


A) 205.1 nm
B) 384.6 nm
C) 683.8 nm
D) 1282 nm
E) > 1500 nm

F) A) and B)
G) A) and C)

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As the frequency of electromagnetic radiation increases, its wavelength also increases.

A) True
B) False

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The de Broglie equation predicts that the wavelength (in m) of a proton moving at 1000. m/s is


A) 3.96 × 10-10 m.
B) 3.96 × 10-7 m.
C) 2.52 × 106 m.
D) 2.52 × 109 m.
E) > 1010 m.

F) All of the above
G) A) and E)

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Electromagnetic radiation of 500 nm wavelength lies in the __________ region of the spectrum.


A) infrared
B) visible
C) ultraviolet
D) X-ray
E) () -ray

F) A) and C)
G) B) and E)

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Which of the following is a correct set of quantum numbers for an electron in a 5f orbital?


A) n = 5, l = 3, ml = +1
B) n = 5, l = 2, ml = +3
C) n = 4, l = 3, ml = 0
D) n = 4, l = 2, ml = +1
E) n = 5, l = 4, ml = 3

F) B) and E)
G) D) and E)

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