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Syn hydrogenation of an alkyne will produce a _________ alkene.

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Cis / Z

Zaitsev's rule states that:


A) In electrophilic addition of an unsymmetrical reagent to an unsymmetrical alkene,the more positive portion of the reagent will become attached to the carbon of the double bond bearing the greater number of hydrogen atoms.
B) An equatorial substituent in cyclohexane results in a more stable conformation than if that substituent were axial.
C) E2 reactions occur only if the β\beta -hydrogen and leaving group can assume an anti-periplanar arrangement.
D) When a reaction forms an alkene,and several possibilities exist,the more (or most) stable isomer is the one which predominates.
E) The order of reactivity of alcohols in dehydration reactions is 3º > 2º > 1º.

F) A) and D)
G) B) and E)

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What is the major product for the following reaction? What is the major product for the following reaction?   A)    B)    C)    D)    E)


A)
What is the major product for the following reaction?   A)    B)    C)    D)    E)
B)
What is the major product for the following reaction?   A)    B)    C)    D)    E)
C)
What is the major product for the following reaction?   A)    B)    C)    D)    E)
D)
What is the major product for the following reaction?   A)    B)    C)    D)    E)
E)
What is the major product for the following reaction?   A)    B)    C)    D)    E)

F) A) and B)
G) B) and C)

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A compound X with the formula C7H10 undergoes catalytic hydrogenation to produce a compound Y with the formula C7H14.What could be true of X?


A) X might have one triple bond and one ring.
B) X might have two double bonds and one ring.
C) X might have one double bond and two rings.
D) X might have one double bond and one triple bond.
E) More than one of the above

F) D) and E)
G) B) and C)

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What is the major product for the following reaction? What is the major product for the following reaction?   A)    B)    C)    D)    E)


A)
What is the major product for the following reaction?   A)    B)    C)    D)    E)
B)
What is the major product for the following reaction?   A)    B)    C)    D)    E)
C)
What is the major product for the following reaction?   A)    B)    C)    D)    E)
D)
What is the major product for the following reaction?   A)    B)    C)    D)    E)
E)
What is the major product for the following reaction?   A)    B)    C)    D)    E)

F) A) and B)
G) A) and E)

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Which molecule would have the lowest heat of hydrogenation? Which molecule would have the lowest heat of hydrogenation?   A)  I B)  II C)  III D)  IV E)  V


A) I
B) II
C) III
D) IV
E) V

F) All of the above
G) B) and C)

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Which would be the major product of the following reaction? Which would be the major product of the following reaction?   A)  I B)  II C)  III D)  IV E)  V


A) I
B) II
C) III
D) IV
E) V

F) None of the above
G) A) and C)

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When an elimination reaction gives the less substituted alkene as the major product,we say that the elimination follows ________________'s rule.

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Which compound listed below would you expect to be the major product when 2-bromo-2-methylbutane is refluxed with KOH/ethanol?


A)
Which compound listed below would you expect to be the major product when 2-bromo-2-methylbutane is refluxed with KOH/ethanol? A)    B)    C)    D)    E)
B)
Which compound listed below would you expect to be the major product when 2-bromo-2-methylbutane is refluxed with KOH/ethanol? A)    B)    C)    D)    E)
C)
Which compound listed below would you expect to be the major product when 2-bromo-2-methylbutane is refluxed with KOH/ethanol? A)    B)    C)    D)    E)
D)
Which compound listed below would you expect to be the major product when 2-bromo-2-methylbutane is refluxed with KOH/ethanol? A)    B)    C)    D)    E)
E)
Which compound listed below would you expect to be the major product when 2-bromo-2-methylbutane is refluxed with KOH/ethanol? A)    B)    C)    D)    E)

F) A) and B)
G) B) and D)

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Which one of the following alcohols would dehydrate most rapidly when treated with sulfuric acid? Which one of the following alcohols would dehydrate most rapidly when treated with sulfuric acid?   A)  I B)  II C)  III D)  IV E)  V


A) I
B) II
C) III
D) IV
E) V

F) C) and E)
G) A) and D)

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What is the major product for the following reaction sequence? What is the major product for the following reaction sequence?   A)    B)    C)    D)    E)  None of the above


A)
What is the major product for the following reaction sequence?   A)    B)    C)    D)    E)  None of the above
B)
What is the major product for the following reaction sequence?   A)    B)    C)    D)    E)  None of the above
C)
What is the major product for the following reaction sequence?   A)    B)    C)    D)    E)  None of the above
D)
What is the major product for the following reaction sequence?   A)    B)    C)    D)    E)  None of the above
E) None of the above

F) C) and E)
G) D) and E)

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Which reaction would yield 2-butyne?


A) CH3C \equiv C: - Na + + CH3Br \rightarrow
B) CH3CH2Br + HC \equiv C: - Na + \rightarrow
C) CH3: - Na + + HC \equiv CCH3 \rightarrow
D) More than one of these
E) None of these

F) C) and D)
G) A) and B)

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Which reaction conditions would not yield 2-butyne from 1-propyne?


A)
Which reaction conditions would not yield 2-butyne from 1-propyne? A)    B)    C)    D)    E)  More than one of these
B)
Which reaction conditions would not yield 2-butyne from 1-propyne? A)    B)    C)    D)    E)  More than one of these
C)
Which reaction conditions would not yield 2-butyne from 1-propyne? A)    B)    C)    D)    E)  More than one of these
D)
Which reaction conditions would not yield 2-butyne from 1-propyne? A)    B)    C)    D)    E)  More than one of these
E) More than one of these

F) A) and B)
G) B) and C)

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Which would be the major product of the following reaction sequence? Which would be the major product of the following reaction sequence?   A)    B)    C)    D)    E)  None of the above


A)
Which would be the major product of the following reaction sequence?   A)    B)    C)    D)    E)  None of the above
B)
Which would be the major product of the following reaction sequence?   A)    B)    C)    D)    E)  None of the above
C)
Which would be the major product of the following reaction sequence?   A)    B)    C)    D)    E)  None of the above
D)
Which would be the major product of the following reaction sequence?   A)    B)    C)    D)    E)  None of the above
E) None of the above

F) B) and E)
G) A) and E)

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Which reaction would not be a method for preparing 5-methyl-1-hexyne?


A)
Which reaction would not be a method for preparing 5-methyl-1-hexyne? A)    B)    C)    D)    E)
B)
Which reaction would not be a method for preparing 5-methyl-1-hexyne? A)    B)    C)    D)    E)
C)
Which reaction would not be a method for preparing 5-methyl-1-hexyne? A)    B)    C)    D)    E)
D)
Which reaction would not be a method for preparing 5-methyl-1-hexyne? A)    B)    C)    D)    E)
E)
Which reaction would not be a method for preparing 5-methyl-1-hexyne? A)    B)    C)    D)    E)

F) A) and D)
G) A) and E)

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Which alkene would liberate the most heat per mole when subjected to catalytic hydrogenation?


A)
Which alkene would liberate the most heat per mole when subjected to catalytic hydrogenation? A)    B)    C)    D)    E)
B)
Which alkene would liberate the most heat per mole when subjected to catalytic hydrogenation? A)    B)    C)    D)    E)
C)
Which alkene would liberate the most heat per mole when subjected to catalytic hydrogenation? A)    B)    C)    D)    E)
D)
Which alkene would liberate the most heat per mole when subjected to catalytic hydrogenation? A)    B)    C)    D)    E)
E)
Which alkene would liberate the most heat per mole when subjected to catalytic hydrogenation? A)    B)    C)    D)    E)

F) A) and C)
G) A) and E)

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A

How will you prepare trans-2-heptene from 2-heptyne?

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Dissolving metal red...

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What is the major product of the reaction, What is the major product of the reaction,   A)  (CH<sub>3</sub>) <sub>2</sub>C=C(CH<sub>3</sub>) <sub>2</sub> B)  (CH<sub>3</sub>) <sub>3</sub>C-CH=CH<sub>2</sub> C)  (CH<sub>3</sub>) <sub>2</sub>C=CHCH<sub>3</sub> D)  (CH<sub>3</sub>) <sub>2</sub>C=CHCH<sub>2</sub>CH<sub>3</sub> E)  None of these


A) (CH3) 2C=C(CH3) 2
B) (CH3) 3C-CH=CH2
C) (CH3) 2C=CHCH3
D) (CH3) 2C=CHCH2CH3
E) None of these

F) C) and D)
G) B) and E)

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Heats of hydrogenation data would be useful in comparing the relative stabilities of which of the following substances? Heats of hydrogenation data would be useful in comparing the relative stabilities of which of the following substances?   A)  I,II,III B)  III,IV C)  I,II,V D)  Heats of hydrogenation data would not be a useful way to compare relative stabilities of any of the substances. E)  All of the above substances could effectively be compared using heats of hydrogenation data.


A) I,II,III
B) III,IV
C) I,II,V
D) Heats of hydrogenation data would not be a useful way to compare relative stabilities of any of the substances.
E) All of the above substances could effectively be compared using heats of hydrogenation data.

F) C) and E)
G) A) and B)

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What is the major product for the following reaction? What is the major product for the following reaction?   A)    B)    C)    D)    E)


A)
What is the major product for the following reaction?   A)    B)    C)    D)    E)
B)
What is the major product for the following reaction?   A)    B)    C)    D)    E)
C)
What is the major product for the following reaction?   A)    B)    C)    D)    E)
D)
What is the major product for the following reaction?   A)    B)    C)    D)    E)
E)
What is the major product for the following reaction?   A)    B)    C)    D)    E)

F) A) and B)
G) A) and C)

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E

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