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Exam 21: Carboxylic Acid Derivatives

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Question 41

Multiple Choice

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_{Cyclic esters are called:}

A) lactones.
B) lactams.
C) lacrimals.
D) imides.
E) enamines.

F) A) and B)
G) A) and C)

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Question 42

Multiple Choice

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The hydrolysis of esters in base is called:

A) the Fischer esterification.
B) the Hunsdiecker reaction.
C) the Dieckmann condensation.
D) transesterification.
E) saponification.

F) None of the above
G) A) and C)

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Question 43

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Predict the major product of the following reaction.

Ethylene glycol will react with phosgene to produce what organic compound?

What type of compound results from the reaction of ethyl formate with cyclohexylamine?

Provide the major organic product in the reaction shown below.

Two equivalents of methyl magnesium bromide will add to:

Arrange the carboxylic acid derivatives below in order of increasing reactivity towards nucleophilic acyl substitution.

Lithium aluminum hydride reduces carboxylic acids, acid chlorides, and esters to:

Provide the name of CH₃O₂CH₂CH₂CH₂CH₃.

Provide the proper IUPAC name for the compound below.

A correct order of reactivity of acid derivatives towards nucleophilic attack is:

Using potential energy diagrams, explain why alkoxides act as leaving groups in nucleophilic acyl substitutions but not in S_N2 reactions.

Predict the major product of the following reaction.

Provide the major organic product in the reaction shown below.

Provide the structure of N,N-diethylbutanamide.

Predict the major product of the following reaction.

Draw the product resulting from the following reaction. Indicate any relevant stereochemistry.

Which of the following is the most reactive carboxylic acid derivative?

What compound results when ethyl benzoate is stirred in methanol containing a trace of HCl and by what name is this process known?